Note to Self

With the fall semester of genchem winding down, I’m imagining how the lab will look next year. Although this may not all get accomplished in the first year, the major features of the tech component I’m trying to develop should be:

A central website that has:
- short movies showing critical lab techniques
- an online version of the lab procedures with links to the movies and other useful information
- prelab powerpoint presentations with links to prelab quizzes
- a shared database of data gathered in lab
- a way to access individual student data as well as lab-averaged data
- simulation tools that the students can use pre- and post-lab to help understand the analysis techniques and quantitatively investigate how
certain errors affect calculated results.

I’m building simulation tools in Excel and will be trying to integrate Flash to provide a way to graphically manipulate the terms in critical equations (I have no idea what I’m doing yet, but I just got my hands on a copy of Flash). This spring and summer I’ll need to build the website, make some movies, and whip up some useful simulations. The IT’s at UMW are going to have to help me with (a) the database stuff, (b) integrating the movies with the site, and (c) think about how to integrate the Flash/Excel simulation stuff into the site.

I think that’s all for now. Bye, blog.

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Some Excel Toys

Part of what I want to do is have students use computer simulations as tools for experimenting with “what-if” scenarios related to the labs they do. There are many great simulations of general scientific phenomena out there, like the ones from the folks at PhET, but I need ones that correspond to the actual labs we conduct. So, I’m working on simulations that might fill this need.

Here are some prototypes that I’ve made for General Chemistry (you may need to download these to play with them - sometimes the macros don’t work via the web - in which case you’ll also need to allow macros to run when you open them):

Mass % NaHCO3 in Alka Seltzer

Empirical Formula of a Hydrate

Thermochemistry

Granted, these may not make much sense without the context I would give students, but here’s a quick overview.

NaHCO3 Lab: Students use increasing amounts of acid to liberate the CO2 from alkaseltzer and then use reaction stoichiometry to find out how much NaHCO3 (sodium bicarbonate) was in the original tablet. The simulation lets you see what happens when you change the mass of the tablet or the concentration of the acid.

Hydrate Lab: Similar in spirit to the NaHCO3 lab in that students determine the composition of something by a measurement of mass loss. Here, they are finding the number of moles of water in a hydrate by heating a hydrated salt to dryness. They know the identity of the salt, so they can calculate the moles of salt and moles of water and then get the empirical formula of the hydrate. The simulation allows you choose different hydrates, see what happens when the heating efficiency is lowered, and to see what happens when you change the mass of the hydrate.

Thermochemistry Lab: Students mix various amounts of calcium chloride into water and observe the temperature change (a calorimetry experiment) to determine the heat of solution of calcium chloride. This requires them to interpolate a maximum temperature change from heating and cooling portions of the curve. The simulation allows you to adjust the heat of solution, the mass of the salt or water, the stirring efficiency (in the lab, this needs to be done well - they are trying to dissolve a solid), and the insulation efficiency of the calorimeter. They also are shown how the interpolation process works.

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What am I Thinking?

General Chemistry laboratory is possibly the best place to instill both enthusiam for and understanding of chemistry in undergraduates. The hands-on experience combined with strange phenomena they’ve never seen before engages their interest and stirs their curiosity. Unfortunately, the traditional approach to lab instruction - prelab lecture followed by an experiment and a write up - doesn’t use the venue for all it could be worth as a teaching tool. First, it doesn’t necessarily work as a means of developing intuition about the chemical principles encountered in lecture, because the prelab lecture means almost nothing without the students having seen (or done) the actual experiment. This was nicely described by Pasl Jalil in the Journal of Chemical Education in 2006. Second, it most definitely doesn’t seem to be a good way to introducing students to managing experimental data.

The failure of the traditional mode of genchemlab is quite evident in students’ lab reports. They tend to focus extreme attention on the mechanics of the calculations and consider chemical principles only as an afterthought when answering discussion questions. It is often the case that no chemical logic or even common sense is present in their discussions. For example, they have a very difficult time offering quantitative explanations for errors they may have encountered, and frequently their explanations run opposite to what one would expect if attention had been paid to chemical principles.

I suspect that problems such as this have three main sources. First, beginning students have very little skill at making observations and forming hypotheses to explain what they observe. Second, as instructors, we require (and rightly so) that students pay attention to details such as proper recording of data, use of notebooks, correct significant figures and rounding in calculations, all of which tends to focus students in lab on the bits and pieces and not on the larger ideas they are encountering. Finally, the sheer volume of new material that the students are encountering is intimidating and frequently overwhelming; in their efforts to assimilate this material, they seem to have little time or brain power left to dedicate to developing a simple skill – scientific common sense.

My goal in this project is to make the general chemistry lab experience more thought provoking, with an emphasis on understanding the chemistry that is occurring while it is occurring as opposed to having the students try to piece together the puzzle of what happened after the fact. I have two basic hypotheses. First, too much time is often spent on experimentation, which makes it difficult for the instructor to engage with students about the experiment and what it is telling them. Second, post-lab lectures based on fresh experimental results would offer a distinct advantage to pre-lab lectures in terms of increasing the students’ comprehension and retention of the chemical principles encountered in lab.

Ideally, the students would be able to generate a real-time common database of their experimental data. By compiling all of their results into an averaged data set, the students would have access to better quality data on which to base their scientific interpretations. This is an advantage to strong and weak students alike. Some kind of remote data entry system to enter results into the database (a laptop) would be needed. After the database is complete (or perhaps when it is close to complete), the instructor would be able to use the results to illustrate any of several principles: measurements and errors; the relationship between physical measurements and underlying chemical principles; data handling and analysis; assessing experimental error in the lab.

This all requires that the technology allow the instructor to access the data in lab, perform relevant calculations with the data that provide quantitative results as quickly as possible for discussion, and simulate hypothetical situations to see how the results respond to things such as experimental errors or altered experimental conditions. It sounds like Steve Gallik has something of the sort going in his biology labs (where is his site?). I am also curious to know whether something like InterChemNet or possibly UbiquitousPresenter would help meet this need.

I still imagine students using traditional notebooks and submitting the pages with their lab reports. They would also be required to demonstrate the ability to perform all calculations leading to reported results regardless of what the technology is able to calculate for them. Giving them access to automatically calculated results in the database/lab interface program is akin to having the answers in the back of the book – the number is known, but they must know how to get to that number.

The system I imagine would give the students not just the “answers” but also the ability to run hypothetical experiments - I’m building some Excel spreadsheets (”toys”) for this purpose. With these, they will gain a tool to help them critically evaluate why the results change as they do when an error occurs or when a procedure is altered.

In the development of this lab model, some questions will need to be addressed such as: What is the role of prelab lectures in a model that emphasizes post-lab lectures?; Is there a way to enhance the use of traditional notebooks within the proposed technology?; What role should online student collaboration play?; Can the technology be made to enhance in-lab collaborations? Feel free to add more…

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